N,N‐Diethyl­pyrrolidinium penta­chloro­(tetra­hydro­furan)­zirconate(IV)

Both ions of the title compound, (C8H18N)[ZrCl5(C4H8O)], exhibit approximate Cs symmetry. The equatorial Cl atoms of the anion display an umbrella effect with significant bending towards the tetra­hydro­furan fragment, as observed before for similar anions. The cation exhibits bond lengths and angle...

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Bibliographic Details
Published inActa crystallographica. Section E, Structure reports online Vol. 62; no. 12; pp. m3267 - m3268
Main Authors Braunschweig, Holger, Kraft, Mario, Seeler, Fabian
Format Journal Article
LanguageEnglish
Published 5 Abbey Square, Chester, Cheshire CH1 2HU, England International Union of Crystallography 01.12.2006
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Summary:Both ions of the title compound, (C8H18N)[ZrCl5(C4H8O)], exhibit approximate Cs symmetry. The equatorial Cl atoms of the anion display an umbrella effect with significant bending towards the tetra­hydro­furan fragment, as observed before for similar anions. The cation exhibits bond lengths and angles in the expected range.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536806045880