Diaqua­(2,2′‐diamino‐4,4′‐bi‐1,3‐thia­zole‐κ2N3,N3′)nickel(II) (pyridine‐2,6‐dicarboxyl­ato‐κ3O,N,O′)nickelate(II) penta­hydrate

The crystal structure of the title compound, [Ni(C6H6N4S2)2(H2O)2][Ni(C7H3NO4)2]·5H2O, consists of NiII complex cations, NiII complex anions and five uncoordinated water mol­ecules. In both the complex cation and anion, the NiII ions assume a distorted octa­hedral coordination. There is extensive hy...

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Published inActa crystallographica. Section E, Structure reports online Vol. 62; no. 9; pp. m2180 - m2182
Main Authors Zhang, Liang‐Jun, Liu, Bing‐Xin, Ge, Hang‐Qun, Xu, Duan‐Jun
Format Journal Article
LanguageEnglish
Published 5 Abbey Square, Chester, Cheshire CH1 2HU, England Blackwell Publishing Ltd 01.09.2006
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Summary:The crystal structure of the title compound, [Ni(C6H6N4S2)2(H2O)2][Ni(C7H3NO4)2]·5H2O, consists of NiII complex cations, NiII complex anions and five uncoordinated water mol­ecules. In both the complex cation and anion, the NiII ions assume a distorted octa­hedral coordination. There is extensive hydrogen bonding between water mol­ecules, complex cations and complex anions.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536806031473