Di‐μ‐pyridyl‐1:2κ2N:C2;2:1κ2N:C2‐μ‐tetra­hydro­furan‐κ2O:O‐bis­[bromo­(tetra­hydro­furan)magnesium(II)] tetra­hydro­furan hemisolvate

The title compound, [Mg2Br2(C5H4N)2(C4H8O)3]·0.5C4H8O, contains dimeric associations of Mg atoms bridged by tetra­hydro­furan (THF) mol­ecules. The coordination polyhedron of the Mg atom is a slightly distorted MgCNO2Br trigonal bipyramid with two THF mol­ecules in the axial positions. One O atom oc...

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Published inActa crystallographica. Section E, Structure reports online Vol. 62; no. 5; pp. m1094 - m1096
Main Authors Churakov, Andrei V., Krut'ko, Dmitry P., Borzov, Maxim V., Kirsanov, Roman S., Belov, Sergei A., Howard, Judith A. K.
Format Journal Article
LanguageEnglish
Published 5 Abbey Square, Chester, Cheshire CH1 2HU, England Blackwell Publishing Ltd 01.05.2006
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Summary:The title compound, [Mg2Br2(C5H4N)2(C4H8O)3]·0.5C4H8O, contains dimeric associations of Mg atoms bridged by tetra­hydro­furan (THF) mol­ecules. The coordination polyhedron of the Mg atom is a slightly distorted MgCNO2Br trigonal bipyramid with two THF mol­ecules in the axial positions. One O atom occupies a site with symmetry 2.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536806013742