(C4H12N2)[Zn2(PO4)(HPO4)(H2PO4)], a layered zinc phosphate with inter­calated N‐methyl­propane‐1,3‐diaminium cations

The title compound, catena‐poly[[N‐methyl­propane‐1,3‐diaminium [μ‐phosphato‐(μ‐hydrogen phosphato)(μ‐dihydrogen phosphato)dizincate(II)]], {(C4H14N2)[Zn2(PO4)(HPO4)(H2PO4)]}n, consists of macroanionic [Zn2(PO4)(HPO4)(H2PO4)]2− layers and inter­calated (C4H12N2)2+ cations. The layers are built up fr...

Full description

Saved in:
Bibliographic Details
Published inActa crystallographica. Section E, Structure reports online Vol. 61; no. 7; pp. m1354 - m1356
Main Authors Rajić, Nevenka, Zabukovec Logar, Nataša, Golobič, Amalija, Stojaković, Djordje, Šajić, Sanja, Kaučič, Venčeslav
Format Journal Article
LanguageEnglish
Published 5 Abbey Square, Chester, Cheshire CH1 2HU, England Munksgaard International Publishers 01.07.2005
Online AccessGet full text

Cover

More Information
Summary:The title compound, catena‐poly[[N‐methyl­propane‐1,3‐diaminium [μ‐phosphato‐(μ‐hydrogen phosphato)(μ‐dihydrogen phosphato)dizincate(II)]], {(C4H14N2)[Zn2(PO4)(HPO4)(H2PO4)]}n, consists of macroanionic [Zn2(PO4)(HPO4)(H2PO4)]2− layers and inter­calated (C4H12N2)2+ cations. The layers are built up from ZnO4 and PO4/HPO4/H2PO4 tetra­hedra that result in small channels of approximate diameter 3.7 Å within the layers. Framework‐to‐framework O—H⋯O and template‐to‐framework N—H⋯O hydrogen bonds are important in stabilizing the structure.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536805018908