Cover Feature: Borate Hydrides as a New Material Class: Structure, Computational Studies, and Spectroscopic Investigations on Sr5(BO3)3H and Sr5(11BO3)3D (Chem. Eur. J. 51/2020)

New anion combination: Borate hydride Sr5(BO3)3H and deuteride Sr5(11BO3)3D were prepared and studied using a number of characterization methods, including 1H solid‐state MAS NMR and vibrational spectroscopy together with quantum chemical calculations as well as X‐ray and neutron powder diffraction....

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Published inChemistry : a European journal Vol. 26; no. 51; p. 11657
Main Authors Wylezich, Thomas, Valois, Renaud, Suta, Markus, Mutschke, Alexander, Ritter, Clemens, Meijerink, Andries, Karttunen, Antti J., Kunkel, Nathalie
Format Journal Article
LanguageEnglish
Published 10.09.2020
Subjects
borate
europium
hydride
luminescence
neutron diffraction
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Summary:New anion combination: Borate hydride Sr5(BO3)3H and deuteride Sr5(11BO3)3D were prepared and studied using a number of characterization methods, including 1H solid‐state MAS NMR and vibrational spectroscopy together with quantum chemical calculations as well as X‐ray and neutron powder diffraction. Doped with Eu2+, broad‐band orange‐red emission under violet excitation can be observed, highlighting the potential of the compound class as host material for optical applications. More information can be found in the Full Paper by T. Wylezich, N. Kunkel et al. on page 11742.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.202003310