beta-acarbose .2. The preparation of various carbohydrate trifluoromethanesulfonates

• Published in: Australian journal of chemistry Vol. 50; no. 3; pp. 197 - 202
• Main Authors: McAuliffe, JC, Stick, RV
• Format: Journal Article
• Language: English
• Published: COLLINGWOOD C S I R O PUBLICATIONS 01.01.1997
• Subjects: Chemistry; Chemistry, Multidisciplinary; Physical Sciences; Science & Technology; OXIDATION; ALCOHOLS; ACTIVATED DIMETHYL-SULFOXIDE

Three carbohydrate trifluoromethanesulfonates, of potential use in the alkylation of a 1-epivalienamine derivative to produce precursors of beta-acarbose, have been prepared from the appropriate alcohols. The conversion of two of these trifluoromethanesulfonates into the primary amine, via the corre...