beta-acarbose .2. The preparation of various carbohydrate trifluoromethanesulfonates

Three carbohydrate trifluoromethanesulfonates, of potential use in the alkylation of a 1-epivalienamine derivative to produce precursors of beta-acarbose, have been prepared from the appropriate alcohols. The conversion of two of these trifluoromethanesulfonates into the primary amine, via the corre...

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Bibliographic Details
Published inAustralian journal of chemistry Vol. 50; no. 3; pp. 197 - 202
Main Authors McAuliffe, JC, Stick, RV
Format Journal Article
LanguageEnglish
Published COLLINGWOOD C S I R O PUBLICATIONS 01.01.1997
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
OXIDATION
ALCOHOLS
ACTIVATED DIMETHYL-SULFOXIDE
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Summary:Three carbohydrate trifluoromethanesulfonates, of potential use in the alkylation of a 1-epivalienamine derivative to produce precursors of beta-acarbose, have been prepared from the appropriate alcohols. The conversion of two of these trifluoromethanesulfonates into the primary amine, via the corresponding azide, is also reported.
ISSN:0004-9425
DOI:10.1071/C96152