Dimethyl 3-chloropropene-2-phospnonate .1. Synthesis through oxidative chlorophosphorylation of allyl chloride

An effective method for the synthesis of dimethyl 3-chloropropene-2-phosphonate (2) in a overall yield of 25% has been developed. The method is based on oxidative chlorophosphorylation of 3-chloropropene followed by elimination of hydrochloric acid and esterification.

Saved in:
Bibliographic Details
Published inPhosphorus and sulfur and the related elements Vol. 101; no. 1-4; pp. 267 - 272
Main Authors Gurevich, IE, Tebby, JC, Dogadina, AV, Ionin, BI
Format Journal Article
LanguageEnglish
Published READING Taylor & Francis 01.01.1995
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
PHOSPHONIC-ACIDS
ammonium salt
3-chloropropene-2-phosphonate
ANALOG
ISOMERIZATION
oxidative chlorophosphorylation
TERMINAL ALKYNES
Online AccessGet more information

Cover

More Information
Summary:An effective method for the synthesis of dimethyl 3-chloropropene-2-phosphonate (2) in a overall yield of 25% has been developed. The method is based on oxidative chlorophosphorylation of 3-chloropropene followed by elimination of hydrochloric acid and esterification.
ISSN:0308-664X
DOI:10.1080/10426509508042526