THE CHEMISTRY OF 5-OXODIHYDROISOXAZOLES .13. REACTIONS OF THE IMINO CARBENE DERIVED FROM PHOTOLYSIS OF ETHYL 5-OXO-2-PHENYL-2,5-DIHYDROISOXAZOLE-4-CARBOXYLATE

Photolysis of ethyl 5-oxo-2-phenyl-2,5-dihydroisoxazole-4-carboxylate at 300 nm in acetonitrile gives a carbene which is captured efficiently by bromide, chloride, acetate and cyanate, and less efficiently by iodide, thiocyanate, cyclohexene and tetrahydrofuran. No hydrogen abstraction or reaction w...

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Bibliographic Details
Published inAustralian journal of chemistry Vol. 48; no. 3; pp. 567 - 575
Main Authors ANG, KH, PRAGER, RH, WILLIAMS, CM
Format Journal Article
LanguageEnglish
Published COLLINGWOOD C S I R O PUBLICATIONS 01.01.1995
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
ALCOHOLS
AMINES
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Summary:Photolysis of ethyl 5-oxo-2-phenyl-2,5-dihydroisoxazole-4-carboxylate at 300 nm in acetonitrile gives a carbene which is captured efficiently by bromide, chloride, acetate and cyanate, and less efficiently by iodide, thiocyanate, cyclohexene and tetrahydrofuran. No hydrogen abstraction or reaction with double bonds was evident.
ISSN:0004-9425
DOI:10.1071/CH9950567