PREPARATION OF CHIRAL STATIONARY PHASES BASED ON ANIONICALLY POLYMERIZED (4S,5S)-4-METHYL-5-PHENYL-2-(4-VINYLPHENYL)-2-OXAZOLINE

(4S,5S)-4-methyl-5-phenyl-2-(4-vinylphenyl)-2-oxazoline (1) was prepared. The anionic polymerisation of 1 was initiated in toluene with butyllithium (BuLi) at -78-degrees-C to afford poly(1) of narrow molecular weight distribution. The resulting poly(1) was immobilised on modified silica gel to give...

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Bibliographic Details
Published inMacromolecular chemistry and physics Vol. 195; no. 12; pp. 3863 - 3868
Main Authors TERFLOTH, G, BLASCHKE, G
Format Journal Article
LanguageEnglish
Published BASEL Huthig & Wepf Verlag 01.12.1994
Subjects
Physical Sciences
Polymer Science
Science & Technology
METHACRYLATE
CHROMATOGRAPHIC RESOLUTION
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Summary:(4S,5S)-4-methyl-5-phenyl-2-(4-vinylphenyl)-2-oxazoline (1) was prepared. The anionic polymerisation of 1 was initiated in toluene with butyllithium (BuLi) at -78-degrees-C to afford poly(1) of narrow molecular weight distribution. The resulting poly(1) was immobilised on modified silica gel to give chiral stationary phases for the separation of racemic compounds.
ISSN:1022-1352
DOI:10.1002/macp.1994.021951212