TI COMPOUNDS WITH FULVALENE BRIDGES - STRUCTURE OF [CPTIBR]2(C10H8, O).TOLUENE

The green Ti(IV) compounds which are obtained by treating titanocene with HCl or Br2 form, on reaction with MeLi and subsequent hydrolysis, the following compounds containing fulvalene bridges: [CpTiCl]2(C10H8,O) (3(Cl)) and [CpTiBr]2(C10H8,O) (3(Br)). Their structures have been determined by X-ray...

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Bibliographic Details
Published inJournal of organometallic chemistry Vol. 447; no. 1; pp. 45 - 50
Main Authors WOHRLE, T, THEWALT, U
Format Journal Article
LanguageGerman
Published LAUSANNE 1 Elsevier 23.03.1993
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
COMPLEXES
TITANOCENE
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Summary:The green Ti(IV) compounds which are obtained by treating titanocene with HCl or Br2 form, on reaction with MeLi and subsequent hydrolysis, the following compounds containing fulvalene bridges: [CpTiCl]2(C10H8,O) (3(Cl)) and [CpTiBr]2(C10H8,O) (3(Br)). Their structures have been determined by X-ray crystallography.
ISSN:0022-328X
DOI:10.1016/0022-328X(93)80271-C