2-FUNCTIONALIZED AND 8-FUNCTIONALIZED 1,4,7,10-TETRAOXASPIRO[5.5]UNDECANES .1. SYNTHESIS OF (+/-)-E,E AND (+/-)-Z,E STRUCTURES

The synthesis of (+/-)-E,E and (+/-)-Z,E 2,8-dihydroxymethyl-1,4,7,10-tetraoxaspiro[5.5]undecane is described. The selective modification of one sidechain is examined for the (+/-)-E,E isomer, and a tetraoxygenated analogue of a commonly encountered insect pheromone is prepared.

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Bibliographic Details
Published inTetrahedron Vol. 49; no. 13; pp. 2621 - 2628
Main Authors LEMAIRE, M, JEMINET, G, GOURCY, JG, DAUPHIN, G
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier 26.03.1993
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
CALCIMYCIN
CHEMISTRY
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Summary:The synthesis of (+/-)-E,E and (+/-)-Z,E 2,8-dihydroxymethyl-1,4,7,10-tetraoxaspiro[5.5]undecane is described. The selective modification of one sidechain is examined for the (+/-)-E,E isomer, and a tetraoxygenated analogue of a commonly encountered insect pheromone is prepared.
ISSN:0040-4020
DOI:10.1016/S0040-4020(01)86341-9