A NOVEL REGIO-SPECIFIC AND STEREO-SPECIFIC HYDROACETOXYLATION REACTION OF 2-ALKYNOIC ACID-DERIVATIVES

2-Alkynoic acid derivatives were hydroacetoxylated regio- and stereo-specifically by reaction with lithium acetate in HOAc at rt under the catalysis of palladium acetate to afford 3-acetoxy-2(Z)-alkenoic acid derivatives.

Saved in:
Bibliographic Details
Published inTetrahedron letters Vol. 33; no. 47; pp. 7205 - 7206
Main Authors LU, XY, ZHU, GX, MA, SM
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier 17.11.1992
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
Online AccessGet more information

Cover

More Information
Summary:2-Alkynoic acid derivatives were hydroacetoxylated regio- and stereo-specifically by reaction with lithium acetate in HOAc at rt under the catalysis of palladium acetate to afford 3-acetoxy-2(Z)-alkenoic acid derivatives.
ISSN:0040-4039
DOI:10.1016/S0040-4039(00)60873-0