DIASTEREOSELECTIVE CYCLIZATION OF ALLYSILANES ON ALPHA-ACYLIMINIUM IONS - A NEW APPROACH TO (+/-)-MYRTINE AND (+/-)-EPIMYRTINE

Total synthesis of (+/-)-myrtine and (+/-)-epimyrtine is described using an intramolecular allylsilane N-acyliminium ion cyclization.

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Bibliographic Details
Published inTetrahedron letters Vol. 33; no. 1; pp. 73 - 76
Main Authors GELASMIALHE, Y, GRAMAIN, JC, LOUVET, A, REMUSON, R
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier 01.01.1992
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ACYLIMINIUM ION
EPIMYRTINE
ALLYLSILANE
MYRTINE
ALKALOIDS
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Summary:Total synthesis of (+/-)-myrtine and (+/-)-epimyrtine is described using an intramolecular allylsilane N-acyliminium ion cyclization.
ISSN:0040-4039
DOI:10.1016/S0040-4039(00)77676-3