FUNCTIONAL ALLENYLSILANES - REGIOSELECTIVE SYNTHESIS OF ALPHA-CHLORINATED OR OMEGA-CHLORINATED TRIMETHYLSILYLALLENYL ALCOHOLS USING ORGANOALUMINUM COMPOUNDS

In many cases, the reaction between alpha- or omega-chloro carbonyl derivatives and organoaluminium compound prepared from Me3Si-C = C-CH2Br is chemo- and regioselective: it affords, in a good yield, trimethylsilyl alpha-allenyl alcohols alpha'- or omega'-substituted by a chlorine atom; so...

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Bibliographic Details
Published inJournal of organometallic chemistry Vol. 403; no. 3; pp. 299 - 309
Main Authors MESNARD, D, MIGINIAC, L
Format Journal Article
LanguageFrench
Published LAUSANNE Elsevier 19.02.1991
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
EPOXIDES
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Summary:In many cases, the reaction between alpha- or omega-chloro carbonyl derivatives and organoaluminium compound prepared from Me3Si-C = C-CH2Br is chemo- and regioselective: it affords, in a good yield, trimethylsilyl alpha-allenyl alcohols alpha'- or omega'-substituted by a chlorine atom; some of these functional alcohols have produced oxygenated heterocycles.
ISSN:0022-328X
DOI:10.1016/0022-328X(91)86476-7