SYNTHESIS OF AMERICANIN-D

By regioselective self-coupling with silver oxide as oxidant the 2,3-trans-2-phenylbenzofuran 8 was synthesized in good yield. Reduction of 8 led in an unambiguous way to americanin-D (rac-1). Synthetic and natural product were identical in every respect.

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Bibliographic Details
Published inLiebigs Annalen der Chemie no. 4; pp. 357 - 360
Main Authors ANTUS, S, BAUER, R, GOTTSEGEN, A, SELIGMANN, O, WAGNER, H
Format Journal Article
LanguageGerman
Published DEERFIELD BEACH Wiley 01.04.1987
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
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Summary:By regioselective self-coupling with silver oxide as oxidant the 2,3-trans-2-phenylbenzofuran 8 was synthesized in good yield. Reduction of 8 led in an unambiguous way to americanin-D (rac-1). Synthetic and natural product were identical in every respect.
ISSN:0170-2041