A metal free chlorothiolation strategy for synthesis of vinyl sulfides from internal allcynoates

A metal free chlorothiolation approach has been developed for conversion of internal alkynoates to vinyl sulfides and also utilized mild PIDA mediated oxidation to yield the corresponding sulfoxides. (C) 2015 Elsevier Ltd. All rights reserved.

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Bibliographic Details
Published inTetrahedron letters Vol. 56; no. 50; pp. 6965 - 6969
Main Authors Surineni, Naresh, Buragohain, Pori, Saikia, Bishwajit, Barua, Nabin C., Baruah, Rajani K.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier 16.12.2015
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
OXIDATION
SULFOXIDES
ACETYLENES
ANALOGS
Vinyl sulfides
Vinyl sulfoxides
REACTIVITY
Chlorothiolation
Phenyl iodine di acetate
Alkynes
SULFENYL CHLORIDES
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Summary:A metal free chlorothiolation approach has been developed for conversion of internal alkynoates to vinyl sulfides and also utilized mild PIDA mediated oxidation to yield the corresponding sulfoxides. (C) 2015 Elsevier Ltd. All rights reserved.
ISSN:0040-4039
DOI:10.1016/j.tetlet.2015.10.028