[Me2C{SnCH(SiMe3)(2)}(2)](2). A mu-Me2C-bridged tetrastanna tetrahedrane

A spacer-bridged bis(organostannylene) was obtained. In the solid-state it adopts the structure of a doubly-capped tetrahedron. It reacts with elemental oxygen, O-2, giving tin suboxides. Additionally, the first solid state structure of a spacer-bridged diorgano tin dihydride is reported.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 51; no. 1; pp. 153 - 156
Main Authors Wagner, Michael, Lutter, Michael, Zobel, Bernhard, Hiller, Wolf, Prosenc, Marc H., Jurkschat, Klaus
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2015
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
MOLECULAR-STRUCTURE
STANNYLENES
CRYSTAL-STRUCTURE
CAGE COMPOUNDS
ZINTL IONS
COMPOUND
REACTIVITY
P-4 TETRAHEDRON
TIN ATOMS
LIQUID-AMMONIA
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Summary:A spacer-bridged bis(organostannylene) was obtained. In the solid-state it adopts the structure of a doubly-capped tetrahedron. It reacts with elemental oxygen, O-2, giving tin suboxides. Additionally, the first solid state structure of a spacer-bridged diorgano tin dihydride is reported.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc07417c