Reaction of N,N '-bis(trimethylsilyl)dicyandiamide with bis(eta(5)-cyclopentadienylvanadium) dichloride

1,3,5-Tris[bis(eta(5)-cyclopentadienyl)chlorovanadium]melamin is prepared in high yield by the reaction of N,N'-bis(trimethylsilyl)dicyandiamide with bis(eta(5)-cyclopentadienylvanadium) dichloride in tetrahydrofuran. As side products, trimethylchlorosilane and cyclopentadiene formed. Reaction...

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Bibliographic Details
Published inRussian journal of general chemistry Vol. 81; no. 4; pp. 658 - 662
Main Authors Gordetsov, A. S., Zimina, S. V., Saprykina, S. V., Loginova, L. B., Piskunov, A. V., Ur'yash, V. F., Moseeva, E. M.
Format Journal Article
LanguageEnglish
Published NEW YORK Springer Nature 01.04.2011
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
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Summary:1,3,5-Tris[bis(eta(5)-cyclopentadienyl)chlorovanadium]melamin is prepared in high yield by the reaction of N,N'-bis(trimethylsilyl)dicyandiamide with bis(eta(5)-cyclopentadienylvanadium) dichloride in tetrahydrofuran. As side products, trimethylchlorosilane and cyclopentadiene formed. Reaction of N,N'-bis(trimethylsilyl) dicyandiamide with benzoyl chloride results in the formation of tris(benzoyl)melamin.
ISSN:1070-3632
DOI:10.1134/S1070363211040062