Tetrafunctional silanes of the formula type Si(CH2X)(4) (X = SAc, SH, OAc, OH, Br, I)

The tetrafunctional silanes Si(CH(2)SAC)(4) (1), Si(CH2SH)(4) (2), Si(CH(2)OAC)(4) (3), Si(CH2OH)(4) (4), Si(CH2Br)(4) (5), and Si(CH2I)(4) (6) were synthesized, starting from Si(CH2Cl)(4)Compounds 1-6 were characterized by NMR studies (H-1, C-13,Si-29) and elemental analyses, and the silanes 4-6 we...

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Bibliographic Details
Published inOrganometallics Vol. 25; no. 2; pp. 548 - 551
Main Authors Ilg, R, Troegel, D, Burschka, C, Tacke, R
Format Journal Article
LanguageEnglish
Published WASHINGTON Amer Chemical Soc 16.01.2006
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
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Summary:The tetrafunctional silanes Si(CH(2)SAC)(4) (1), Si(CH2SH)(4) (2), Si(CH(2)OAC)(4) (3), Si(CH2OH)(4) (4), Si(CH2Br)(4) (5), and Si(CH2I)(4) (6) were synthesized, starting from Si(CH2Cl)(4)Compounds 1-6 were characterized by NMR studies (H-1, C-13,Si-29) and elemental analyses, and the silanes 4-6 were additionally studied by single-crystal X-ray diffraction. Compounds 1-6 are challenging starting materials for the synthesis of further tetrafunctional silanes of the general formula type Si(CH2X)(4), including compounds with different substituents X.
ISSN:0276-7333
1520-6041
DOI:10.1021/om0580497