Selective O-2 oxidation of air-sensitive lanthanocene thiolates and thioether chelate

Two unusual regioselective O-2 oxidation reactions of air-sensitive lanthanocene thiolates and a thioether chelate are described, revealing a novel oxygenation pattern of thiolate ligands.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 18; pp. 2342 - 2344
Main Authors Zhou, XG, Zhu, M, Zhang, LB, Zhu, ZY, Pi, CF, Pang, Z, Weng, LH, Cai, RF
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2005
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
ORGANOMETALLIC COMPOUNDS
ORGANOLANTHANIDE COMPLEXES
LIGANDS
CHEMISTRY
CRYSTAL-STRUCTURES
SINGLET OXYGEN
LANTHANIDE
CYCLOPENTADIENYL COMPLEXES
NITRILE HYDRATASE
YTTRIUM
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Summary:Two unusual regioselective O-2 oxidation reactions of air-sensitive lanthanocene thiolates and a thioether chelate are described, revealing a novel oxygenation pattern of thiolate ligands.
ISSN:1359-7345
DOI:10.1039/b417609j