Nucleophilic substitution of alkylchlorodihydro[60]fullerenes: thermodynamic stabilities of alkylated C-60 cation intermediates

Thermodynamic stabilities of alkylated C-60 cations (RC60+) were determined based on the activation free energies Of SA solvolysis of the title compounds, indicating that these cations have stabilities comparable to that of the tert-butyl cation.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 24; pp. 3062 - 3063
Main Authors Kitagawa, T, Lee, Y, Hanamura, M, Sakamoto, H, Konno, H, Takeuchi, K, Komatsu, K
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2002
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
FULLERENE CHEMISTRY
STRAIN
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Summary:Thermodynamic stabilities of alkylated C-60 cations (RC60+) were determined based on the activation free energies Of SA solvolysis of the title compounds, indicating that these cations have stabilities comparable to that of the tert-butyl cation.
ISSN:1359-7345
DOI:10.1039/b210126b