Synthesis of a linear assembly consisting of a central Ru(Phen)(3)(2+) derivative and two peripheral porphyrins
A ruthenium(II) precursor complex containing a bis-phenanthroline ligand, leading to a controlled helical structure around the metal centre, and a third phenanthroline-type ligand has been prepared. The spatial arrangement of the system is such that two chemical groups are disposed trans to one anot...
Saved in:
Published in | European journal of organic chemistry Vol. 2002; no. 19; pp. 3276 - 3280 |
---|---|
Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
WEINHEIM
Wiley
01.10.2002
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Summary: | A ruthenium(II) precursor complex containing a bis-phenanthroline ligand, leading to a controlled helical structure around the metal centre, and a third phenanthroline-type ligand has been prepared. The spatial arrangement of the system is such that two chemical groups are disposed trans to one another on an axis running through the Ru centre. By appropriate functional group transformation, these two groups can be attached to monosubstituted zinc(II) porphyrins (PZn) to afford a linear array consisting of a central ruthenium(II) complex and two peripheral PZn motifs. ((C) Wiley-VCH Verlag GrabH, 69451 Weinheim, Germany, 2002). |
---|---|
ISSN: | 1434-193X 1099-0690 |
DOI: | 10.1002/1099-0690(200210)2002:19<3276::AID-EJOC3276>3.0.CO;2-R |