Synthesis of a linear assembly consisting of a central Ru(Phen)(3)(2+) derivative and two peripheral porphyrins

A ruthenium(II) precursor complex containing a bis-phenanthroline ligand, leading to a controlled helical structure around the metal centre, and a third phenanthroline-type ligand has been prepared. The spatial arrangement of the system is such that two chemical groups are disposed trans to one anot...

Full description

Saved in:
Bibliographic Details
Published inEuropean journal of organic chemistry Vol. 2002; no. 19; pp. 3276 - 3280
Main Authors Salom-Roig, XJ, Chambron, JC, Goze, C, Heitz, Sauvage, JP
Format Journal Article
LanguageEnglish
Published WEINHEIM Wiley 01.10.2002
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
IRIDIUM(III)
RU(II) COMPLEXES
PHOTOINDUCED ELECTRON-TRANSFER
linear arrays
PHOTOSYNTHETIC REACTION-CENTER
MODEL
ruthenium
porphyrinoids
donor-acceptor systems
MIMICKING
TRIADS
CHARGE SEPARATION
ENERGY-TRANSFER
BIS 1,10-PHENANTHROLINE LIGAND
Online AccessGet full text

Cover

More Information
Summary:A ruthenium(II) precursor complex containing a bis-phenanthroline ligand, leading to a controlled helical structure around the metal centre, and a third phenanthroline-type ligand has been prepared. The spatial arrangement of the system is such that two chemical groups are disposed trans to one another on an axis running through the Ru centre. By appropriate functional group transformation, these two groups can be attached to monosubstituted zinc(II) porphyrins (PZn) to afford a linear array consisting of a central ruthenium(II) complex and two peripheral PZn motifs. ((C) Wiley-VCH Verlag GrabH, 69451 Weinheim, Germany, 2002).
ISSN:1434-193X
1099-0690
DOI:10.1002/1099-0690(200210)2002:19<3276::AID-EJOC3276>3.0.CO;2-R