A new additive for controlled radical polymerization

A new Versatile additive for the controlled radical polymerization of numerous vinyl monomers under mild conditions is presented. The addition of 1,1-diphenylethene (DPE) to a conventional radical polymerization system consisting of initiator and monomer results in a controlled behavior of the polym...

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Bibliographic Details
Published inMacromolecular rapid communications. Vol. 22; no. 9; pp. 700 - 703
Main Authors Wieland, PC, Raether, B, Nuyken, O
Format Journal Article
LanguageEnglish
Published BERLIN Wiley 06.07.2001
Subjects
Physical Sciences
Polymer Science
Science & Technology
SUBSTITUTED ETHANES
METHYL-METHACRYLATE
INITIATION
CHAIN TRANSFER RAFT
STYRENE
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Summary:A new Versatile additive for the controlled radical polymerization of numerous vinyl monomers under mild conditions is presented. The addition of 1,1-diphenylethene (DPE) to a conventional radical polymerization system consisting of initiator and monomer results in a controlled behavior of the polymerization. Block copolymers are obtained by simply heating the resulting polymers in the presence of a second monomer.
ISSN:1022-1336
DOI:10.1002/1521-3927(20010601)22:9<700::AID-MARC700>3.3.CO;2-A