Highly efficient Kharasch addition catalysed by RuCl(Cp)(PPh3)(2)

Air-stable and readily available RuCl(Cp*)(PPh3)(2) is so far the best ruthenium-based catalyst precursor for promoting the addition of CCl4 and CHCl3 across olefins at a temperature as low as 40 degrees C, (C) 2000 Elsevier Science Ltd, All rights reserved.

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Bibliographic Details
Published inTetrahedron letters Vol. 41; no. 32; pp. 6071 - 6074
Main Authors Simal, F, Wlodarczak, L, Demonceau, A, Noels, AF
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier 05.08.2000
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ORGANIC-SYNTHESIS
radicals and radical reactions
LIGANDS
ruthenium and compounds
catalysis
RADICAL POLYMERIZATION
olefins
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Summary:Air-stable and readily available RuCl(Cp*)(PPh3)(2) is so far the best ruthenium-based catalyst precursor for promoting the addition of CCl4 and CHCl3 across olefins at a temperature as low as 40 degrees C, (C) 2000 Elsevier Science Ltd, All rights reserved.
ISSN:0040-4039
DOI:10.1016/S0040-4039(00)01048-0