Trinuclear palladium(II) complexes with 2-hydroxy-4-methoxyacetophenone N-4-dimethylthiosemicarbazone: Synthesis, spectral studies and crystal structure of a tripalladium complex

The synthesis and spectral characterization of a new triangular, trinuclear palladium(II) complex with the dianion of 2-hydroxy-4-methoxyacetophenone N-4-dimethylthiosemicarbazone, 4MeOAp4Me(2)(2-) is reported. The X-ray crystal structure determination of [Pd(4MeOAp4Me(2))](3). DMSO shows it to cont...

Full description

Saved in:
Bibliographic Details
Published inEuropean journal of inorganic chemistry no. 4; pp. 727 - 734
Main Authors Kovala-Demertzi, D, Kourkoumelis, N, Demertzis, MA, Miller, Frampton, CS, Swearingen, JK, West, DX
Format Journal Article
LanguageEnglish
Published BERLIN Wiley 01.04.2000
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Physical Sciences
Science & Technology
PD(II)
S ligands
MOLECULAR-STRUCTURE
NICKEL(II) COMPLEXES
ANTITUMOR-ACTIVITY
COPPER(II) COMPLEXES
IN-VITRO
one-dimensional extended networks
palladium
2-HYDROXYACETOPHENONE N-4-SUBSTITUTED THIOSEMICARBAZONES
structure elucidation
LIGAND
ACETATE
DERIVATIVES
Online AccessGet full text

Cover

More Information
Summary:The synthesis and spectral characterization of a new triangular, trinuclear palladium(II) complex with the dianion of 2-hydroxy-4-methoxyacetophenone N-4-dimethylthiosemicarbazone, 4MeOAp4Me(2)(2-) is reported. The X-ray crystal structure determination of [Pd(4MeOAp4Me(2))](3). DMSO shows it to contain a chair-type hexagon of alternating Pd and S atoms which form a molecular bowl. The crystal structure of H(2)4MeOAp4Me(2) shows that it is the E isomer with respect to the imine bond of the thiosemicarbazone moiety.
ISSN:1434-1948