Synthesis of 3-perfluoroalkylprop-1-enes R-F-CH2-CH = CH2

The reactions of perfluoroalkyl iodides with allylbromide or chloride, in the presence of solid potassium hydroxide KOH give 3-perfluoroalkylprop-1-enes RFCH2CH=CH2 in good yields under mild conditions. This reaction represents a synthetically viable and convenient route to such compounds. (C) 1999...

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Bibliographic Details
Published inJournal of fluorine chemistry Vol. 99; no. 2; pp. 171 - 175
Main Authors Rubio, S, Blancou, H, Commeyras, A
Format Journal Article
LanguageFrench
Published LAUSANNE Elsevier 01.11.1999
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
PERFLUOROALKYL
3-perfluoroalkylprop-1-enes
FLUORINATED OLEFINS
solid potassium hydroxide
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Summary:The reactions of perfluoroalkyl iodides with allylbromide or chloride, in the presence of solid potassium hydroxide KOH give 3-perfluoroalkylprop-1-enes RFCH2CH=CH2 in good yields under mild conditions. This reaction represents a synthetically viable and convenient route to such compounds. (C) 1999 Elsevier Science S.A. All rights reserved.
ISSN:0022-1139
DOI:10.1016/S0022-1139(99)00137-2