Bismuth (III) chloride; An efficient and selective catalyst for deprotection of 1,1-diacetates

A variety of 1,1-diacetates are easily and efficiently deprotected in the presence of catalytic amounts of bismuth(III) chloride affording the corresponding aldehydes in high yields.

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Bibliographic Details
Published inSynthetic communications Vol. 29; no. 16; pp. 2741 - 2746
Main Authors Mohammadpoor-Baltork, Aliyan, H
Format Journal Article
LanguageEnglish
Published NEW YORK Marcel Dekker Inc 01.01.1999
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
EXPANSIVE GRAPHITE
GEMINAL DIACETATES
BENZALDEHYDE DIACETATES
ALDEHYDES
FACILE PROCEDURE
CLEAVAGE
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Summary:A variety of 1,1-diacetates are easily and efficiently deprotected in the presence of catalytic amounts of bismuth(III) chloride affording the corresponding aldehydes in high yields.
ISSN:0039-7911
DOI:10.1080/00397919908086439