Synthesis of 8 alpha-acetoxy-2 beta,3 beta-dihydroxy-13,14,15,16-tetranorlabdan-12-oic acid

8,13-Epoxy-3 beta-hydroxylabd-14-en-2-one (1) from the wood of Lagarostrobos colensoi has been converted in 25% overall yield into 8 alpha-acetoxy-2 beta,3 beta-dihydroxy-13,14,15,16-tetranorlabdan-12-oic acid (2), a useful intermediate for synthesis.

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Bibliographic Details
Published inSynthetic communications Vol. 28; no. 4; pp. 659 - 668
Main Authors Cambie, RC, Stewart, DR
Format Journal Article
LanguageEnglish
Published NEW YORK Marcel Dekker Inc 01.01.1998
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
PODOCARPACEAE
CHEMISTRY
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Summary:8,13-Epoxy-3 beta-hydroxylabd-14-en-2-one (1) from the wood of Lagarostrobos colensoi has been converted in 25% overall yield into 8 alpha-acetoxy-2 beta,3 beta-dihydroxy-13,14,15,16-tetranorlabdan-12-oic acid (2), a useful intermediate for synthesis.
ISSN:0039-7911
DOI:10.1080/00397919808005938