Role of ammonium sulfate in sulfurization flotation of azurite:Inhibiting the formation of copper sulfide colloid and its mechanism

• Published in: 矿业科学技术学报（英文版） Vol. 32; no. 3; pp. 575 - 584
• Main Authors: Jinpeng Cai, Chao Su, Yinyu Ma, Xingcai Yu, Rong Peng, Jiangli Li, Xiaolin Zhang, Jianjun Fang, Peilun Shen, Dianwen Liu
• Format: Journal Article
• Language: English
• Published: State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization,Yunnan Key Laboratory of Green Separation and Enrichment of Strategic Metal Resources,Faculty of Land Resources Engineering,Kunming University of Science and Technology,Kunming 650093,China%Shandong Gold Group Co.,Ltd,Jinan 250014,China%Yunnan Posphate Group Co.,Ltd,Kunming 650600,China 2022
• Subjects: Crystal growth; Ammonium sulfate; Inhibition; Azurite; Sulfurization flotation; Colloid
• ISSN: 2095-2686
• DOI: 10.3969/j.issn.2095-2686.2022.03.011

In this study,the role of(NH4)2SO4 during the sulfurization of azurite and its response to flotation were investigated.The flotation results showed that adding(NH4)2SO4 prior to sulfurization decreased the for-mation of colloid in flotation pulp,and the floatability of the suppressed azurite caused by excess sodium sulfide was restored.After adding(NH4)2SO4 prior to sulfurization,the formation of Cu(NH3)2n+interme-diate products changed the path of the sulfurization reaction,which slowed the direct impact of HS-on the azurite surface.The nucleation rate was reduced,and the growth of copper sulfide crystal was improved.Covellite(syn,CuS)with larger crystal grains was formed on the azurite surface,thereby enhancing the mechanical stability of copper sulfide products onto the mineral surface.Therefore,the generated copper sulfide colloid significantly reduced,ultimately promoting the effective adsorption of xanthate on the azurite surface.