An effective co-modification strategy to enhance the cycle stability of LiNiCoMnO for lithium-ion batteries

• Published in: RSC advances Vol. 13; no. 48; pp. 34194 - 34199
• Main Authors: Zhou, Jingjing, Wei, Bingxin, Liu, Meng, Qin, Yinping, Cheng, Hongyu, Lyu, Yingchun, Liu, Yang, Guo, Bingkun
• Format: Journal Article
• Published: 22.11.2023
• ISSN: 2046-2069
• DOI: 10.1039/d3ra04145j

Ni-rich cathode materials suffer from rapid capacity fading caused by interface side reactions and bulk structure degradation. Previous studies show that Co is conducive to bulk structure stability and sulfate can react with the residual lithium (LiOH and Li 2 CO 3 ) on the surface of Ni-rich cathode materials and form a uniform coating to suppress the side reactions between the cathode and electrolyte. Here, CoSO 4 is utilized as a modifier for LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM811) cathode materials. It reacts with the residual lithium on the surface of the NCM811 cathode to form Li-ion conductive Li 2 SO 4 protective layers and Co doping simultaneously during the high-temperature sintering process, which can suppress the side reactions between the Ni-rich cathode and electrolyte and effectively prevent the structural transformation. As a result, the co-modified NCM811 cathode with 3 wt% CoSO 4 exhibits an improved cycling performance of 81.1% capacity retention after 200 cycles at 1C and delivers an excellent rate performance at 5C of 187.4 mA h g −1 , which is 10.2% higher than that of the pristine NCM811 cathode. A co-modified NCM811 cathode material with Co doping and a Li 2 SO 4 coating is obtained by reaction of CoSO 4 modifier with residual lithium via a one-step facile method.