Waste heat recovery using thermally responsive ionic liquids through TiO nanopore and macroscopic membranes

• Published in: Energy & environmental science Vol. 16; no. 1; pp. 4539 - 4548
• Main Authors: Pascual, Marc, Chapuis, Nicolas, Abdelghani-Idrissi, Soufiane, Jullien, Marie-Caroline, Siria, Alessandro, Bocquet, Lydéric
• Format: Journal Article
• Published: 11.10.2023
• ISSN: 1754-5692; 1754-5706
• DOI: 10.1039/d3ee00654a

Waste heat is the untapped heat produced by a thermodynamic process. It is usually released into the surrounding environment without any valorization. But recently, industrial waste heat has been identified as a promising energy source and many techniques have been proposed for its recovery. In this paper we present a method to convert low temperature waste heat ( T < 100 °C) into salinity gradients, from which osmotic power is harvested across a nanoporous membrane. The heat is used to trigger the phase separation of a lower critical solution temperature (LCST) water-ionic liquid mixture. The two phases, of different salt concentrations, are fed in two reservoirs separated by a membrane with nanopores 30-100 nm in diameter. An osmotic electric current is measured across the membrane for various concentration ratios and pHs, the origin of which is shown to be a diffusio-osmotic (DO) process occurring at the TiO 2 pore surface. The power density across the nanoporous TiO 2 membrane is found to reach 7 W m −2 . This opens up new avenues for the harvesting of waste-heat using nanoporous membranes and ionic liquids in a closed-loop configuration. Waste heat is the untapped heat produced by a thermodynamic process. It is usually released in the surrounding environment without any valorization. Entropic harvesting of phase-changing liquids across TiO 2 membrane via diffusio-osmotic transport of ions is demonstrated.