Phase transition behaviour and mechanism of 2D TiO(B) nanosheets through water-mediated removal of surface ligands

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 52; no. 42; pp. 1559 - 15596
• Main Authors: Xie, Shirui, Fan, Lijing, Chen, Yanxin, Cai, Jiliang, Wu, Fan, Cao, Kecheng, Liu, Pengxin
• Format: Journal Article
• Published: 31.10.2023
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/d3dt02752j

Phase engineering is a central subject in materials research. The recent research interest in the phase transition behavior of atomically thin 2D materials reveals the important role of their surface chemistry. In this study, we investigated the phase transformation of ultrathin TiO 2 (B) nanosheets to anatase under different conditions. We found that the convenient transformation in water under ambient conditions is driven by the hydrolysis of surface 1,2-ethylenedioxy groups and departure of ethylene glycol. A transformation pathway through the formation of protonic titanate is proposed. The ultrathin structure and the metastable nature of the precursor facilitate the phase conversion to anatase. Our finding offers a new insight into the mechanism of TiO 2 (B) phase transition from the viewpoint of surface chemistry and may contribute to the potential application of ultrathin TiO 2 (B) nanosheets in aqueous environments. Phase transition of ultrathin TiO 2 (B) nanosheets to anatase TiO 2 is much easier in water phase than in air, due to a surficial hydrolysis reaction.