MoO nanowire growth on VO/WO for thermochromic applications

This study explores the structural, electronic, and optical properties of sandwich-structured thin films composed of WO 3 , MoWO 3 , and MoO 3 as window layers on VO 2 /WO 3 via a physical vapor deposition method. Morphological analysis demonstrates the evolution of distinct nanowires, offering insi...

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Bibliographic Details
Published inPhysical chemistry chemical physics : PCCP Vol. 26; no. 6; pp. 5548 - 5557
Main Authors Houimi, Amina, Basyooni- Kabatas, Mohamed A, Yilmaz, Mucahit, Eker, Yasin Ramazan
Format Journal Article
Published 07.02.2024
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Summary:This study explores the structural, electronic, and optical properties of sandwich-structured thin films composed of WO 3 , MoWO 3 , and MoO 3 as window layers on VO 2 /WO 3 via a physical vapor deposition method. Morphological analysis demonstrates the evolution of distinct nanowires, offering insights into the lattice strain of the VO 2 layer toward high-performance thermochromatic devices. Temperature-dependent sheet resistivity is investigated, showcasing significant improvements in conductivity for samples with MoO 3 as a window layer. The electrical and optical properties of the MoO 3 /VO 2 /WO 3 device showed a phase transition temperature ( T c ) of 36.8 °C, a transmittance luminous ( T lum ) of 54.57%, and a solar modulation ability (Δ T sol ) of 12.43. This comprehensive analysis contributes to understanding the growth of nanowires on multi-layered thin films, offering valuable insights into potential applications in bright windows. Strained MoO 3 /VO 2 /WO 3 nanowires showed a phase transition temperature ( T c ) of 36.8 °C, a transmittance luminous ( T lum ) of 54.57%, and a solar modulation ability (Δ T sol ) of 12.43.
Bibliography:https://doi.org/10.1039/d3cp05942a
Electronic supplementary information (ESI) available. See DOI
ISSN:1463-9076
1463-9084
DOI:10.1039/d3cp05942a