Visible and near-infrared luminescence properties of Nd/Yb co-doped GdO phosphors for highly sensitive optical thermometry

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 51; no. 27; pp. 1612 - 1622
• Main Authors: Zhang, Yuhong, Wang, Pengcheng, Wang, Haiyan, Zheng, Xingke, Guo, Yibin, Zhang, Nan, Liu, Hang
• Format: Journal Article
• Published: 12.07.2022
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/d2dt01271e

Phosphors with rare earth (RE) ions are widely applied to optical temperature measurements. Moreover, the near-infrared (NIR) emission of phosphors has potential applications in the biological field. Herein, Gd 2 O 3 : x %Nd 3+ /Yb 3+ (0.2 ≤ x ≤ 0.8) samples are successfully synthesized by the sol-gel method, and their phase and morphology are characterized. The XRD data are refined by Rietveld. Under 980 nm continuous wave (CW) laser excitation, the upconversion (UC) and downshift (DS) emissions are studied. The temperature sensing performances of thermally coupled levels (TCLs) and non-thermally coupled levels (non-TCLs) of Gd 2 O 3 : Nd 3+ /Yb 3+ phosphors are investigated through the fluorescence intensity ratio (FIR) technology. In the temperature range of 303-523 K, the maximum relative sensitivity of I 761 nm / I 550 nm reaches 6.54% K −1 , which is based on non-TCLs. At the same time, the maximum relative sensitivity of I 761 nm / I 1000 nm-1500 nm reaches 3.13%. In addition, the influence of the laser induced heating (LIH) effect is studied. Compared with square wave (SW) pumping, the relative sensitivity would decrease at CW excitation. Finally, the durability and temperature uncertainty are also discussed. The results prove that the Gd 2 O 3 :Nd 3+ /Yb 3+ samples present higher relative sensitivity and durability and lower temperature uncertainty in the biological window. Therefore, the phosphors can be used as optical thermometers in the biological field. The temperature sensing performances of non-thermally coupled levels of Gd 2 O 3 :Nd 3+ /Yb 3+ phosphors are investigated through the fluorescence intensity ratio technology. The maximum relative sensitivity of I 761 nm / I 550 nm reaches 6.54% K −1 .