Controlling thermoelectric transport native defects in the diamond-like semiconductors CuHgGeTe and HgGeTe
Diamond like semiconductors (DLS) have emerged as candidates for thermoelectric energy conversion. Towards understanding and optimizing performance, we present a comprehensive investigation of the electronic properties of two DLS phases, quaternary Cu 2 HgGeTe 4 and related ordered vacancy compound...
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Published in | Journal of materials chemistry. A, Materials for energy and sustainability Vol. 9; no. 46; pp. 26189 - 2621 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Published |
30.11.2021
|
Online Access | Get full text |
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Summary: | Diamond like semiconductors (DLS) have emerged as candidates for thermoelectric energy conversion. Towards understanding and optimizing performance, we present a comprehensive investigation of the electronic properties of two DLS phases, quaternary Cu
2
HgGeTe
4
and related ordered vacancy compound Hg
2
GeTe
4
, including thermodynamic stability, defect chemistry, and transport properties. To establish the thermodynamic link between the related but distinct phases, the stability region for both is visualized in chemical potential space. In spite of their similar structure and bonding, we show that the two materials exhibit reciprocal behaviors for dopability. Cu
2
HgGeTe
4
is degenerately p-type in all environments despite its wide stability region, due to the presence of low-energy acceptor defects V
Cu
and Cu
Hg
and is resistant to extrinsic n-type doping. Meanwhile Hg
2
GeTe
4
has a narrow stability region and intrinsic behavior due to the relatively high formation energy of native defects, but presents an opportunity for bi-polar doping. While these two compounds have similar structure, bonding, and chemical constituents, the reciprocal nature of their dopability emerges from significant differences in band edge positions. A Brouwer band diagram approach is utilized to visualize the role of native defects on carrier concentrations, dopability, and transport properties. This study elucidates the doping asymmetry between two solid-solution forming DLS phases Cu
2
HgGeTe
4
and Hg
2
GeTe
4
by revealing the defect chemistry of each compound, and suggests design strategies for defect engineering of DLS phases.
Defect analysis and phase boundary mapping of Cu
2
HgGeTe
4
and Hg
2
GeTe
4
reveal reciprocal doping potential despite their similar crystal structures. Measurements validate predictions of Cu
2
HgGeTe
4
as highly degenerate and Hg
2
GeTe
4
as an intrinsic semiconductor. |
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Bibliography: | 10.1039/d1ta07410e Electronic supplementary information (ESI) available. See DOI |
ISSN: | 2050-7488 2050-7496 |
DOI: | 10.1039/d1ta07410e |