Ultrafast-charging and long cycle-life anode materials of TiO-bronze/nitrogen-doped graphene nanocomposites for high-performance lithium-ion batteries

• Published in: RSC advances Vol. 1; no. 71; pp. 43811 - 43824
• Main Authors: Autthawong, Thanapat, Chimupala, Yothin, Haruta, Mitsutaka, Kurata, Hiroki, Kiyomura, Tsutomu, Yu, Ai-shui, Chairuangsri, Torranin, Sarakonsri, Thapanee
• Format: Journal Article
• Published: 08.12.2020
• ISSN: 2046-2069
• DOI: 10.1039/d0ra07733j

Emerging technologies demand a new generation of lithium-ion batteries that are high in power density, fast-charging, safe to use, and have long cycle lives. This work reports charging rates and specific capacities of TiO 2 (B)/N-doped graphene (TNG) composites. The TNG composites were prepared by the hydrothermal method in various reaction times (3, 6, 9, 12, and 24 h), while the N-doped graphene was synthesized using the modified Hummer's method followed by a heat-treatment process. The different morphologies of TiO 2 dispersed on the N-doped graphene sheet were confirmed as anatase-nanoparticles (3, 6 h), TiO 2 (B)-nanotubes (9 h), and TiO 2 (B)-nanorods (12, 24 h) by XRD, TEM, and EELS. In electrochemical studies, the best battery performance was obtained with the nanorods TiO 2 (B)/N-doped graphene (TNG-24h) electrode, with a relatively high specific capacity of 500 mA h g −1 at 1C (539.5 mA g −1 ). In long-term cycling, excellent stability was observed. The capacity retention of 150 mA h g −1 was observed after 7000 cycles, at an ultrahigh current of 50C (27.0 A g −1 ). The synthesized composites have the potential for fast-charging and have high stability, showing potential as an anode material in advanced power batteries for next-generation applications. The TiO 2 -bronze/nitrogen-doped graphene nanocomposites have the potential for fast-charging and have high stability, showing potential as an anode material in advanced power batteries for next-generation applications.