Palladium-catalyzed selective B(3)-H arylation of -carboranes with arylboronic acids at room temperature

A palladium-catalyzed selective B(3)-H arylation of o -carboranes at room temperature has been developed using readily available arylboronic acids as the aryl source, and the corresponding 3-aryl- o -carboranes were obtained in good to excellent yields. This method provides a powerful synthetic rout...

Full description

Saved in:
Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 57; no. 13; pp. 1655 - 1658
Main Authors Yang, Ziyi, Wu, Yuanbo, Fu, Yatong, Yang, Jianxin, Lu, Jian, Lu, Ju-You
Format Journal Article
Published 17.02.2021
Online AccessGet full text

Cover

More Information
Summary:A palladium-catalyzed selective B(3)-H arylation of o -carboranes at room temperature has been developed using readily available arylboronic acids as the aryl source, and the corresponding 3-aryl- o -carboranes were obtained in good to excellent yields. This method provides a powerful synthetic route for constructing polysubstituted o -carborane derivatives. A palladium-catalyzed selective B(3)-H arylation of o -carboranes under room temperature has been developed using readily available arylboronic acids as the aryl source, and the corresponding 3-aryl- o -carboranes were obtained in good to excellent yields.
Bibliography:For ESI and crystallographic data in CIF or other electronic format see DOI
2043212
10.1039/d0cc07591d
4j
and
3l
(CIF). CCDC
2031426
Electronic supplementary information (ESI) available: Full experimental details and characterization of all compounds (PDF), X-ray crystallographic data for
(CIF), X-ray crystallographic data for
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc07591d