Chemo-mechanical strain effects on band engineering of the TiO photocatalyst for increasing the water splitting activity

• Published in: Journal of materials chemistry. A, Materials for energy and sustainability Vol. 8; no. 3; pp. 1335 - 1346
• Main Authors: Kim, Yoonyoung, Watanabe, Motonori, Matsuda, Junko, Staykov, Aleksandar, Kusaba, Hajime, Takagaki, Atsushi, Akbay, Taner, Ishihara, Tatsumi
• Format: Journal Article
• Language: English
• Published: 22.01.2020
• ISSN: 2050-7488; 2050-7496
• DOI: 10.1039/c9ta11048h

Photocatalytic water splitting is the most ideal system to harvest solar energy for the production of useful chemicals. There have been many attempts to increase the photocatalytic activity of the TiO 2 photocatalyst, such as loading co-catalysts and dopants, and the introduction of oxygen vacancies. Strain effects have also attracted much interest to increase the charge mobility in bulk oxide. Here, we report on the effectiveness of tensile strain in stabilizing the anatase phase of TiO 2 at high temperature and increasing the photocatalytic activity by an increase in the charge separation with a unique mixed phase structure. The rate of H 2 formation over TiO 2 was decreased upon spark plasma sintering (SPS) treatment because of a decrease in the surface area; however, SPS treatment with Au dispersion significantly increased the H 2 formation rate to higher than that over commercially available P-25 TiO 2 (no SPS treatment) loaded with Au. The O 2 formation rate was also increased by strain effects in TiO 2 . Furthermore, strain effects were effective for visible light sensitivity on TiO 2 . Tensile strain induced by dispersion of Au particles is effective for stabilizing the anatase phase of TiO 2 at high temperature and also increasing the photocatalytic activity by an increase in the charge separation with band engineering.