Dual copper- and photoredox-catalysed C(sp2)-C(sp3) couplingElectronic supplementary information (ESI) available: Experimental procedures, full optimisation and control studies, mechanistic studies, characterisation data and copies of NMR spectra of new compounds. See DOI: 10.1039/c9cc01718f

The use of copper catalysis with visible light photoredox catalysis in a cooperative fashion has recently emerged as a versatile means of developing new C-C bond forming reactions. In this work, dual copper and photoredox catalysis is exploited to effect C(sp 2 )-C(sp 3 ) cross-couplings between ary...

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Main Authors McLean, Euan B, Gauchot, Vincent, Brunen, Sebastian, Burns, David J, Lee, Ai-Lan
Format Journal Article
Published 04.04.2019
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Summary:The use of copper catalysis with visible light photoredox catalysis in a cooperative fashion has recently emerged as a versatile means of developing new C-C bond forming reactions. In this work, dual copper and photoredox catalysis is exploited to effect C(sp 2 )-C(sp 3 ) cross-couplings between aryl boronic acids and benzyl bromides. The use of copper catalysis with visible light photoredox catalysis in a cooperative fashion has recently emerged as a versatile means of developing new C-C bond forming reactions. In this work, dual copper and photoredox catalysis is exploited to effect C(sp 2 )-C(sp 3 ) cross-couplings between aryl boronic acids and benzyl bromides.
Bibliography:10.1039/c9cc01718f
Electronic supplementary information (ESI) available: Experimental procedures, full optimisation and control studies, mechanistic studies, characterisation data and copies of NMR spectra of new compounds. See DOI
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc01718f