Synthesis of chiral carbazole-based BODIPYs showing circularly polarized luminescenceElectronic supplementary information (ESI) available: Experimental procedures and compound data. CCDC 1885421-1885423. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9cc00894b

Chiral carbazole-based BODIPYs with a binaphthyl unit were synthesized via an Al-mediated reaction. Et 2 AlCl was found to be a convenient reagent for the reaction to give the chiral BODIPYs in high yields. It has been shown for the first time that these chiral carbazole-based BODIPYs show circularl...

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Bibliographic Details
Main Authors Maeda, Chihiro, Nagahata, Keiji, Takaishi, Kazuto, Ema, Tadashi
Format Journal Article
LanguageEnglish
Published 07.03.2019
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Summary:Chiral carbazole-based BODIPYs with a binaphthyl unit were synthesized via an Al-mediated reaction. Et 2 AlCl was found to be a convenient reagent for the reaction to give the chiral BODIPYs in high yields. It has been shown for the first time that these chiral carbazole-based BODIPYs show circularly polarized luminescence (CPL) both in solution and in the solid state. Chiral carbazole-based BODIPYs with a binaphthyl unit were synthesized via an Al-mediated reaction.
Bibliography:For ESI and crystallographic data in CIF or other electronic format see DOI
Electronic supplementary information (ESI) available: Experimental procedures and compound data. CCDC
10.1039/c9cc00894b
1885421-1885423
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc00894b