An aqueous medium-controlled stereospecific oxidative iodination of alkynes: efficient access to (E)-diiodoalkene derivativesIICT-Manuscript communication number: IICT/Pubs./2018/290.Electronic supplementary information (ESI) available: Spectroscopic data of all products. See DOI: 10.1039/c8nj03929a

A new and versatile approach for the stereospecific iodination of alkynes using cheap, air stable and non-toxic reagents in aqueous media has been developed. This protocol is tolerant of various functional groups, and provides a broad range of vicinal diiodoalkenes with exceptional E -selectivity un...

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Main Authors Banothu, Rammurthy, Peraka, Swamy, Kodumuri, Srujana, Chevella, Durgaiah, Gajula, Krishna Sai, Amrutham, Vasu, Yennamaneni, Divya Rohini, Nama, Narender
Format Journal Article
Published 05.11.2018
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Abstract A new and versatile approach for the stereospecific iodination of alkynes using cheap, air stable and non-toxic reagents in aqueous media has been developed. This protocol is tolerant of various functional groups, and provides a broad range of vicinal diiodoalkenes with exceptional E -selectivity under mild conditions. Scale-up reactions (up to 5 g) established the proficiency of this protocol and highlight the feasibility of large scale reactions. A new and versatile approach for the stereospecific iodination of alkynes has been developed in aqueous media. Scale-up reactions (up to 5 g) established the proficiency of this protocol and highlight the feasibility of large scale reactions.
AbstractList A new and versatile approach for the stereospecific iodination of alkynes using cheap, air stable and non-toxic reagents in aqueous media has been developed. This protocol is tolerant of various functional groups, and provides a broad range of vicinal diiodoalkenes with exceptional E -selectivity under mild conditions. Scale-up reactions (up to 5 g) established the proficiency of this protocol and highlight the feasibility of large scale reactions. A new and versatile approach for the stereospecific iodination of alkynes has been developed in aqueous media. Scale-up reactions (up to 5 g) established the proficiency of this protocol and highlight the feasibility of large scale reactions.
Author Nama, Narender
Yennamaneni, Divya Rohini
Chevella, Durgaiah
Banothu, Rammurthy
Kodumuri, Srujana
Amrutham, Vasu
Gajula, Krishna Sai
Peraka, Swamy
AuthorAffiliation Academy of Scientific and Innovative Research, CSIR-Indian Institute of Chemical Technology
C&FC Division, CSIR-Indian Institute of Chemical Technology
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Notes Electronic supplementary information (ESI) available: Spectroscopic data of all products. See DOI
10.1039/c8nj03929a
IICT-Manuscript communication number: IICT/Pubs./2018/290.
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  publication-title: Formation of Carbon-Halogen Bonds (Cl, Br, I), in The Chemistry of Functional Groups, Supplement D2: The Chemistry of Halides, Pseudo Halides and Azides
  doi: Sasson
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