An aqueous medium-controlled stereospecific oxidative iodination of alkynes: efficient access to (E)-diiodoalkene derivativesIICT-Manuscript communication number: IICT/Pubs./2018/290.Electronic supplementary information (ESI) available: Spectroscopic data of all products. See DOI: 10.1039/c8nj03929a

A new and versatile approach for the stereospecific iodination of alkynes using cheap, air stable and non-toxic reagents in aqueous media has been developed. This protocol is tolerant of various functional groups, and provides a broad range of vicinal diiodoalkenes with exceptional E -selectivity un...

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Main Authors Banothu, Rammurthy, Peraka, Swamy, Kodumuri, Srujana, Chevella, Durgaiah, Gajula, Krishna Sai, Amrutham, Vasu, Yennamaneni, Divya Rohini, Nama, Narender
Format Journal Article
Published 05.11.2018
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Summary:A new and versatile approach for the stereospecific iodination of alkynes using cheap, air stable and non-toxic reagents in aqueous media has been developed. This protocol is tolerant of various functional groups, and provides a broad range of vicinal diiodoalkenes with exceptional E -selectivity under mild conditions. Scale-up reactions (up to 5 g) established the proficiency of this protocol and highlight the feasibility of large scale reactions. A new and versatile approach for the stereospecific iodination of alkynes has been developed in aqueous media. Scale-up reactions (up to 5 g) established the proficiency of this protocol and highlight the feasibility of large scale reactions.
Bibliography:Electronic supplementary information (ESI) available: Spectroscopic data of all products. See DOI
10.1039/c8nj03929a
IICT-Manuscript communication number: IICT/Pubs./2018/290.
ISSN:1144-0546
1369-9261
DOI:10.1039/c8nj03929a