Highly hydrothermal stable mesoporous molecular sieves (TZM) prepared by the self assembly of zeolitic subunits from ZSM-5 desilication and their catalytic performance for CO2 reforming of CH4Electronic supplementary information (ESI) available. See DOI: 10.1039/c8nj03861a
We demonstrated a new strategy for the preparation of highly stable mesoporous molecular sieves (TZM) by the desilication of ZSM-5 zeolite and self-assembly of the zeolite subunits in a Na 2 O·(3.3-3.4) SiO 2 aqueous solution. Na 2 O·(3.3-3.4) SiO 2 in the aqueous solution plays two roles in the syn...
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Main Authors | , , , , |
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Format | Journal Article |
Language | English |
Published |
19.11.2018
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Online Access | Get full text |
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Summary: | We demonstrated a new strategy for the preparation of highly stable mesoporous molecular sieves (TZM) by the desilication of ZSM-5 zeolite and self-assembly of the zeolite subunits in a Na
2
O·(3.3-3.4) SiO
2
aqueous solution. Na
2
O·(3.3-3.4) SiO
2
in the aqueous solution plays two roles in the synthesis, one is providing a moderate alkaline medium with a buffering effect for the desilication of ZSM-5 zeolite, and the other one is supplementing the silica source. The desilication of ZSM-5 zeolite was optimized by the adjustment of reaction temperature and time, and pH of the solution. TZM were characterized by X-ray diffraction (XRD), N
2
adsorption/desorption (BET), Fourier transform infrared (FT-IR) spectroscopy and transmission electron microscopy (TEM). The characterization results show that the characteristics of ZSM-5 zeolite, such as double six-membered or five-membered ring subunits, were still preserved in TZM, and TZM possessed the well-ordered mesostructure of ZSM-5 zeolite crystals. Compared with the pure silica mesoporous molecular sieve (Si-MCM-41, 4 days), the hydrothermal stability of TZM (8 days) was increased by 100% in refluxed water. The significant improvement of TZM hydrothermal stability was due to an increase of the surface hydrophobicity and the ratio of 5-rings or 6-rings, and a remarkable decrease in the number of hydrophilic silanol groups. After hydrothermal treatment for 8 days, TZM also exhibited a more efficient catalytic activation than Si-MCM-41 treated for 4 days in the CO
2
reforming of methane reaction at 1023 K (750 °C). The 5% Ni/TZM-8-Glu (5 wt% Ni, loading) catalyst prepared by a glucose modified impregnation method exhibited excellent catalytic activity, which provided 73% CH
4
and 72.5% CO
2
conversion at 1023 K (750 °C).
We demonstrated a new strategy for the preparation of highly stable mesoporous molecular sieves (TZM) by the desilication of ZSM-5 zeolite and self-assembly of the zeolite subunits in a Na
2
O·(3.3-3.4) SiO
2
aqueous solution. |
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Bibliography: | 10.1039/c8nj03861a Electronic supplementary information (ESI) available. See DOI |
ISSN: | 1144-0546 1369-9261 |
DOI: | 10.1039/c8nj03861a |