Selective aerobic oxidation of halides and amines with an inorganic-ligand supported zinc catalystElectronic supplementary information (ESI) available: Experimental conditions, supplementary table and NMR spectra. See DOI: 10.1039/c8dt03003k

A practical, efficient and environmentally benign catalytic protocol for the oxidative cross-coupling reaction of halides with amines, oxidative self-coupling of amines and oxidation of halides was developed with inorganic-ligand supported ZnPOM (NH 4 ) 4 [ZnMo 6 O 18 (OH) 6 ] using molecular oxygen...

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Main Authors Wang, Jingjing, Zhai, Yongyan, Wang, Ying, Yu, Han, Zhao, Wenshu, Wei, Yongge
Format Journal Article
Published 02.10.2018
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Summary:A practical, efficient and environmentally benign catalytic protocol for the oxidative cross-coupling reaction of halides with amines, oxidative self-coupling of amines and oxidation of halides was developed with inorganic-ligand supported ZnPOM (NH 4 ) 4 [ZnMo 6 O 18 (OH) 6 ] using molecular oxygen. This method mainly utilizes an inorganic polymolybdate ligand to support the Zn 2+ ion, avoiding the use of complicated organic ligands. A practical, efficient and environmentally benign catalytic protocol for the oxidative cross-coupling reaction of halides with amines, oxidative self-coupling of amines and oxidation of halides was developed with inorganic-ligand supported ZnPOM (NH 4 ) 4 [ZnMo 6 O 18 (OH) 6 ] using molecular oxygen.
Bibliography:10.1039/c8dt03003k
Electronic supplementary information (ESI) available: Experimental conditions, supplementary table and NMR spectra. See DOI
ISSN:1477-9226
1477-9234
DOI:10.1039/c8dt03003k