Probing membrane asymmetry of ABC polymersomesElectronic supplementary information (ESI) available: Experimental details, characterization of polymers, 1H NMR of ABC-biotin, LSM of polymersomes formed by ABC and biotinylated polymers, FCS of ABC labeled with Bodipy 630/650, calculation of polymersome volume, and LSM of cloud-like aggregates. See DOI: 10.1039/c8cc09659g

We report the sensitivity of the membrane asymmetry of ABC (PEO- b -PCL- b -PMOXA) polymersomes towards the end-group modification of a shorter C block. While a non-modified ABC polymer formed polymersomes with the A block outside and the C block inside, a mixture of ABC and ABC-biotin formed polyme...

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Bibliographic Details
Main Authors Konishcheva, Evgeniia V, Daubian, Davy, Rigo, Serena, Meier, Wolfgang P
Format Journal Article
Published 22.01.2019
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Summary:We report the sensitivity of the membrane asymmetry of ABC (PEO- b -PCL- b -PMOXA) polymersomes towards the end-group modification of a shorter C block. While a non-modified ABC polymer formed polymersomes with the A block outside and the C block inside, a mixture of ABC and ABC-biotin formed polymersomes with the C block outside. We report the sensitivity of the membrane asymmetry of ABC (PEO- b -PCL- b -PMOXA) polymersomes towards the end-group modification of a shorter C block.
Bibliography:Electronic supplementary information (ESI) available: Experimental details, characterization of polymers
1
H NMR of ABC-biotin, LSM of polymersomes formed by ABC and biotinylated polymers, FCS of ABC labeled with Bodipy 630/650, calculation of polymersome volume, and LSM of cloud-like aggregates. See DOI
10.1039/c8cc09659g
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc09659g