Identifying reactive organo-selenium precursors in the synthesis of CdSe nanoplateletsElectronic supplementary information (ESI) available. See DOI: 10.1039/c8cc06326e

In the synthesis of CdSe nanoplatelets, the selenium-to-selenide reduction pathway is unknown. We study solvent-free growth of CdSe nanoplatelets and identify bis(acyl) selenides as key reactive intermediates. Based on our findings, we prepare a series of bis(acyl) selenides that provide useful prec...

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Bibliographic Details
Main Authors Riedinger, Andreas, Mule, Aniket S, Knüsel, Philippe N, Ott, Florian D, Rossinelli, Aurelio A, Norris, David J
Format Journal Article
LanguageEnglish
Published 16.10.2018
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Summary:In the synthesis of CdSe nanoplatelets, the selenium-to-selenide reduction pathway is unknown. We study solvent-free growth of CdSe nanoplatelets and identify bis(acyl) selenides as key reactive intermediates. Based on our findings, we prepare a series of bis(acyl) selenides that provide useful precursors with tailored reactivity for liquid-phase syntheses of nanoplatelets. Bis(acyl) selenides are identified as selenium precursors that can provide additional control over the synthesis of CdSe nanoplatelets.
Bibliography:Electronic supplementary information (ESI) available. See DOI
10.1039/c8cc06326e
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc06326e