Anion-π interactions of highly π-acidic dipyridinium-naphthalene diimide saltsElectronic supplementary information (ESI) available: Synthesis procedure, characterization data, including X-ray data and NMR spectra. CCDC 1830674-1830677. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8cc03941k

A highly π-acidic dipyridinium-naphthalene diimide acceptor shows anion-π interactions with halides and PF 6 − . Lewis basicity and redox potential of the anion affect the chemistry, and photophysical and electrochemical properties, as well as both ionic and electrical conductivities. Our results pr...

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Main Authors Tam, Teck Lip Dexter, Ng, Chee Koon, Lu, Xuefeng, Lim, Zheng Long, Wu, Jishan
Format Journal Article
Published 28.06.2018
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Summary:A highly π-acidic dipyridinium-naphthalene diimide acceptor shows anion-π interactions with halides and PF 6 − . Lewis basicity and redox potential of the anion affect the chemistry, and photophysical and electrochemical properties, as well as both ionic and electrical conductivities. Our results provide insights into doping, degradation and ion transport mechanisms in organic n-type semiconductors. A highly π-acidic dipyridinium-naphthalene diimide acceptor shows anion-π interactions with halides and PF 6 − .
Bibliography:Electronic supplementary information (ESI) available: Synthesis procedure, characterization data, including X-ray data and NMR spectra. CCDC
For ESI and crystallographic data in CIF or other electronic format see DOI
1830674-1830677
10.1039/c8cc03941k
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc03941k