Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7Electronic supplementary information (ESI) available: Synthesis details, single crystal X-ray diffraction, DSC, physical property measurements, first-principle calculations. CCDC 1833009 and 1833010. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8cc02563k
The binary bismuthides Nd 3 Bi 7 and Sm 3 Bi 7 were synthesized and structurally characterized for the first time. The results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the...
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| Main Authors | , , |
|---|---|
| Format | Journal Article |
| Published |
21.06.2018
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| Online Access | Get full text |
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| Summary: | The binary bismuthides Nd
3
Bi
7
and Sm
3
Bi
7
were synthesized and structurally characterized for the first time. The results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the corresponding phase diagrams.
Reported, for the very first time, are the synthesis and structures of two new compounds, discovered in well-studied binary phase diagrams. |
|---|---|
| Bibliography: | For ESI and crystallographic data in CIF or other electronic format see DOI 1833009 and Electronic supplementary information (ESI) available: Synthesis details, single crystal X-ray diffraction, DSC, physical property measurements, first-principle calculations. CCDC 1833010 10.1039/c8cc02563k |
| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/c8cc02563k |