Strategies toward realization of unsupported transition metal-boron donor-acceptor complexes: an insight from theoryElectronic supplementary information (ESI) available: Computational details, calculated values of geometrical parameters, correlation plot and Cartesian coordinates. See DOI: 10.1039/c8cc02027b

Pre-pyramidalization of the boron centre in the Lewis acidic groups is a prerequisite for the formation of unsupported donor-acceptor complexes with Lewis basic metal fragments such as [Pt(NHC) 2 ]. Pre-pyramidalization of the boron center is found to be a necessary condition for the realization of...

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Main Authors Borthakur, Bitupon, Das, Sandeep, Phukan, Ashwini K
Format Journal Article
LanguageEnglish
Published 10.05.2018
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Summary:Pre-pyramidalization of the boron centre in the Lewis acidic groups is a prerequisite for the formation of unsupported donor-acceptor complexes with Lewis basic metal fragments such as [Pt(NHC) 2 ]. Pre-pyramidalization of the boron center is found to be a necessary condition for the realization of unsupported metal-boron dative bond.
Bibliography:Electronic supplementary information (ESI) available: Computational details, calculated values of geometrical parameters, correlation plot and Cartesian coordinates. See DOI
10.1039/c8cc02027b
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc02027b